Introduction of the Zhao's Group

 ZHAO's Group has been engaged in the research of composite functional materials, and has made certain research results, in a recent Polyhedron, Inorg. Chem. Acta in major journals published papers, 2 PHDs and 8 masters work in the team.

 1.Study on the design, synthesis and properties of functional metal coordination polymer;

 2.The new methods of organic synthesis and the deuterium generation effect;

 3.Organic-inorganic hybrid materials.

Achievements

Fig.1  a The intrachain hydrogen bonds formed . b The 3D structure established by hydrogen bonds. All H-atoms are omitted for clarity

Fig. 2. The framework structure contains the Cd–Cl bridge in complex 2

Fig. 3. (a) The 1D helical chain structure; (b) perspective view along c axis; (c) the 3D framework

1.Hong Zhao, Zhi-Rong Qu, Heng-Yun Ye and Ren-Gen Xiong.In situ hydrothermal synthesis of tetrazole coordination polymers with
interesting physical properties.Chem. Soc. Rev.2008,37,84–100.
2.Qiong Ye,Xi-Sen Wang,Hong Zhao and Ren-Gen Xiong.Highly stable olefin–Cu(I) coordination oligomers and polymers.Chem. Soc. Rev.2005, 34, 208–225.
3.Shi-Yan Zhou, Zhi-Rong Qu, Hua-Jun Ma, Gai-Gai Wang, Hong Zhao.Hydrothermal Syntheses, Crystal Structure and Characterization
of Two Alkaline Earth Metal Coordination Polymers with 1-(4-
Iodophenyl)-5-methyl-1H-[1,2,3]-triazole-4-carboxylate Ligand.J Inorg Organomet Polym (2014) 24:656–663.
4.Hong Zhao, Zhao-Jing Chu, Gui-Yuan Gao, Huan-Huan Huang, Zhi-Rong Qu.Three coordination polymers of transition metals built using HPPC
ligand: Crystal structures and novel topology.Polyhedron 83 (2014) 143–149.
5.Jin-Long Hong, Zhi-Rong Qu, Hua-Jun Ma, Gai-Gai Wang, and Hong Zhao.Syntheses, Structures, and Characterization of Two Novel Copper(II) and Cadmium(II) Compounds Based on Pyridyl Conjugated 1,2,3-Triazole.Bull. Korean Chem. Soc. 2014, Vol. 35, No. 5.
6.Hong Zhao, Shi-Yan Zhou, Chao Feng, Neng-Xiao Wei, Gai-Gai Wang.Synthesis, characterization and luminescence of Cd(II), Zn(II) complexes with 1,2,3-triazole derivatives and in situ solvothermal decarboxylation of the ligands.Inorganica Chimica Acta 421 (2014) 169–175.